| Rank | Player | Matches | Wins | Losses | PCT | 6-0 | 0-6 |
| 1 | Justine Henin BEL | 12 | 10 | 2 | 0.833 | 1 | 0 |
| 2 | Shahar Peer ISR | 12 | 9 | 3 | 0.750 | 3 | 1 |
| 3 | Serena Williams USA | 11 | 10 | 1 | 0.909 | 1 | 0 |
| 4 | Flavia Pennetta ITA | 10 | 7 | 3 | 0.700 | 2 | 1 |
| 5 | Yanina Wickmayer BEL | 9 | 8 | 1 | 0.889 | 0 | 0 |
| 6 | Alona Bondarenko UKR | 9 | 8 | 1 | 0.889 | 0 | 0 |
| 7 | Victoria Azarenka BLR | 9 | 7 | 2 | 0.778 | 4 | 0 |
| 8 | Jie Zheng CHN | 9 | 7 | 2 | 0.778 | 1 | 2 |
| 9 | Francesca Schiavone ITA | 9 | 6 | 3 | 0.667 | 2 | 2 |
| 10 | Na Li CHN | 9 | 6 | 3 | 0.667 | 1 | 0 |
| 11 | Kim Clijsters BEL | 8 | 7 | 1 | 0.875 | 2 | 2 |
| 12 | Maria Kirilenko RUS | 8 | 6 | 2 | 0.750 | 0 | 1 |
| 13 | Aravane Rezai FRA | 8 | 5 | 3 | 0.625 | 1 | 0 |
| 14 | Daniela Hantuchova SVK | 8 | 5 | 3 | 0.625 | 1 | 0 |
| 15 | Carla Suarez Navarro ESP | 8 | 5 | 3 | 0.625 | 0 | 1 |
| 16 | Sara Errani ITA | 8 | 5 | 3 | 0.625 | 0 | 1 |
| 17 | Elena Dementieva RUS | 7 | 6 | 1 | 0.857 | 0 | 0 |
| 18 | Dominika Cibulkova SVK | 7 | 4 | 3 | 0.571 | 1 | 1 |
| 19 | Nadia Petrova RUS | 7 | 4 | 3 | 0.571 | 1 | 0 |
| 20 | Gisela Dulko ARG | 6 | 4 | 2 | 0.667 | 1 | 1 |
| 21 | Andrea Petkovic GER | 6 | 4 | 2 | 0.667 | 0 | 0 |
| 22 | Ana Ivanovic SRB | 6 | 4 | 2 | 0.667 | 0 | 0 |
| 23 | Svetlana Kuznetsova RUS | 6 | 4 | 2 | 0.667 | 0 | 0 |
| 24 | Dinara Safina RUS | 6 | 4 | 2 | 0.667 | 0 | 0 |
| 25 | Alize Cornet FRA | 6 | 3 | 3 | 0.500 | 2 | 1 |
| 26 | Agnes Szavay HUN | 6 | 3 | 3 | 0.500 | 0 | 0 |
| 27 | Kimiko Date Krumm JPN | 6 | 3 | 3 | 0.500 | 0 | 0 |
| 28 | Anabel Medina Garrigues ESP | 6 | 3 | 3 | 0.500 | 0 | 0 |
| 29 | Roberta Vinci ITA | 6 | 3 | 3 | 0.500 | 0 | 0 |
| 30 | Venus Williams USA | 5 | 4 | 1 | 0.800 | 0 | 0 |
| 31 | Agnieszka Radwanska POL | 5 | 3 | 2 | 0.600 | 3 | 0 |
| 32 | Vera Zvonareva RUS | 5 | 3 | 2 | 0.600 | 2 | 1 |
| 33 | Caroline Wozniacki DEN | 5 | 3 | 2 | 0.600 | 1 | 0 |
| 34 | Anastasia Pavlyuchenkova RUS | 5 | 3 | 2 | 0.600 | 0 | 0 |
| 35 | Samantha Stosur AUS | 5 | 3 | 2 | 0.600 | 0 | 0 |
| 36 | Alla Kudryavtseva RUS | 5 | 2 | 3 | 0.400 | 2 | 1 |
| 37 | Lucie Safarova CZE | 5 | 2 | 3 | 0.400 | 1 | 0 |
| 38 | Casey Dellacqua AUS | 5 | 2 | 3 | 0.400 | 1 | 0 |
| 39 | Alicia Molik AUS | 5 | 2 | 3 | 0.400 | 0 | 1 |
| 40 | Aleksandra Wozniak CAN | 5 | 2 | 3 | 0.400 | 0 | 0 |