| Rank | Player | Matches | Wins | Losses | PCT | 6-0 | 0-6 |
| 1 | Olivier Rochus BEL | 26 | 9 | 17 | 0.346 | 0 | 1 |
| 2 | Igor Andreev RUS | 35 | 18 | 17 | 0.514 | 0 | 3 |
| 3 | Andreas Seppi ITA | 37 | 20 | 17 | 0.541 | 2 | 0 |
| 4 | Nicolas Mahut FRA | 27 | 11 | 16 | 0.407 | 1 | 2 |
| 5 | Jarkko Nieminen FIN | 29 | 13 | 16 | 0.448 | 1 | 0 |
| 6 | Simone Bolelli ITA | 35 | 19 | 16 | 0.543 | 1 | 0 |
| 7 | Marin Cilic CRO | 36 | 20 | 16 | 0.556 | 0 | 0 |
| 8 | Gilles Simon FRA | 37 | 21 | 16 | 0.568 | 0 | 0 |
| 9 | Fernando Verdasco ESP | 40 | 24 | 16 | 0.600 | 3 | 1 |
| 10 | Sergio Roitman ARG | 21 | 6 | 15 | 0.286 | 1 | 2 |
| 11 | Michael Berrer GER | 21 | 6 | 15 | 0.286 | 0 | 2 |
| 12 | Filippo Volandri ITA | 24 | 9 | 15 | 0.375 | 0 | 0 |
| 13 | Oscar Hernandez ESP | 27 | 12 | 15 | 0.444 | 1 | 2 |
| 14 | Albert Montanes ESP | 28 | 13 | 15 | 0.464 | 0 | 2 |
| 15 | Jurgen Melzer AUT | 29 | 14 | 15 | 0.483 | 0 | 1 |
| 16 | Ivo Karlovic CRO | 34 | 19 | 15 | 0.559 | 0 | 0 |
| 17 | Sam Querrey USA | 34 | 19 | 15 | 0.559 | 0 | 1 |
| 18 | Paul-Henri Mathieu FRA | 36 | 21 | 15 | 0.583 | 2 | 0 |
| 19 | Carlos Berlocq ARG | 17 | 3 | 14 | 0.176 | 0 | 2 |
| 20 | Dudi Sela ISR | 20 | 6 | 14 | 0.300 | 1 | 0 |
| 21 | Ivo Minar CZE | 22 | 8 | 14 | 0.364 | 0 | 0 |
| 22 | Benjamin Becker GER | 22 | 8 | 14 | 0.364 | 0 | 2 |
| 23 | Rainer Schuettler GER | 23 | 9 | 14 | 0.391 | 1 | 2 |
| 24 | Potito Starace ITA | 25 | 11 | 14 | 0.440 | 1 | 0 |
| 25 | Feliciano Lopez ESP | 26 | 12 | 14 | 0.462 | 0 | 0 |
| 26 | Marc Gicquel FRA | 28 | 14 | 14 | 0.500 | 2 | 1 |
| 27 | Agustin Calleri ARG | 29 | 15 | 14 | 0.517 | 0 | 1 |
| 28 | Jose Acasuso ARG | 30 | 16 | 14 | 0.533 | 1 | 1 |
| 29 | Ivan Ljubicic CRO | 31 | 17 | 14 | 0.548 | 1 | 1 |
| 30 | Mardy Fish USA | 33 | 19 | 14 | 0.576 | 0 | 0 |
| 31 | Tommy Robredo ESP | 34 | 20 | 14 | 0.588 | 0 | 1 |
| 32 | Kristof Vliegen BEL | 18 | 5 | 13 | 0.278 | 1 | 1 |
| 33 | Victor Hanescu ROU | 18 | 5 | 13 | 0.278 | 1 | 0 |
| 34 | Mischa Zverev GER | 20 | 7 | 13 | 0.350 | 0 | 2 |
| 35 | Vincent Spadea USA | 20 | 7 | 13 | 0.350 | 0 | 0 |
| 36 | Santiago Ventura ESP | 21 | 8 | 13 | 0.381 | 2 | 0 |
| 37 | Robin Haase NED | 25 | 12 | 13 | 0.480 | 1 | 1 |
| 38 | Guillermo Garcia-Lopez ESP | 26 | 13 | 13 | 0.500 | 1 | 3 |
| 39 | Carlos Moya ESP | 27 | 14 | 13 | 0.519 | 1 | 0 |
| 40 | Marat Safin RUS | 27 | 14 | 13 | 0.519 | 1 | 0 |