| Rank | Player | Matches | Wins | Losses | PCT | 6-0 | 0-6 |
| 1 | Andy Roddick USA | 21 | 18 | 3 | 0.857 | 0 | 0 |
| 2 | Marin Cilic CRO | 20 | 17 | 3 | 0.850 | 0 | 1 |
| 3 | Roger Federer SUI | 13 | 11 | 2 | 0.846 | 2 | 0 |
| 4 | Rafael Nadal ESP | 13 | 11 | 2 | 0.846 | 1 | 0 |
| 5 | Andy Murray GBR | 12 | 10 | 2 | 0.833 | 0 | 0 |
| 6 | Nikolay Davydenko RUS | 17 | 14 | 3 | 0.824 | 4 | 2 |
| 7 | Novak Djokovic SRB | 16 | 13 | 3 | 0.813 | 1 | 1 |
| 8 | David Ferrer ESP | 18 | 14 | 4 | 0.778 | 4 | 0 |
| 9 | John Isner USA | 18 | 14 | 4 | 0.778 | 0 | 0 |
| 10 | Juan Monaco ARG | 21 | 16 | 5 | 0.762 | 2 | 1 |
| 11 | Robin Soderling SWE | 12 | 9 | 3 | 0.750 | 1 | 0 |
| 12 | Fernando Gonzalez CHI | 12 | 9 | 3 | 0.750 | 0 | 1 |
| 13 | Juan Martin Del Potro ARG | 4 | 3 | 1 | 0.750 | 0 | 1 |
| 14 | David Nalbandian ARG | 4 | 3 | 1 | 0.750 | 0 | 0 |
| 15 | Juan Carlos Ferrero ESP | 19 | 14 | 5 | 0.737 | 2 | 0 |
| 16 | Fernando Verdasco ESP | 15 | 11 | 4 | 0.733 | 1 | 1 |
| 17 | Marcos Baghdatis CYP | 21 | 15 | 6 | 0.714 | 1 | 2 |
| 18 | Jo-Wilfried Tsonga FRA | 14 | 10 | 4 | 0.714 | 0 | 0 |
| 19 | Mikhail Youzhny RUS | 14 | 10 | 4 | 0.714 | 0 | 0 |
| 20 | Ernests Gulbis LAT | 16 | 11 | 5 | 0.688 | 0 | 0 |
| 21 | Tomas Berdych CZE | 16 | 11 | 5 | 0.688 | 3 | 0 |
| 22 | Ivo Karlovic CRO | 19 | 13 | 6 | 0.684 | 0 | 0 |
| 23 | Thomaz Bellucci BRA | 18 | 12 | 6 | 0.667 | 0 | 1 |
| 24 | Ivan Ljubicic CRO | 12 | 8 | 4 | 0.667 | 0 | 1 |
| 25 | Stephane Robert FRA | 9 | 6 | 3 | 0.667 | 0 | 0 |
| 26 | Stanislas Wawrinka SUI | 9 | 6 | 3 | 0.667 | 0 | 0 |
| 27 | Lleyton Hewitt AUS | 6 | 4 | 2 | 0.667 | 2 | 0 |
| 28 | Dustin Brown JAM | 3 | 2 | 1 | 0.667 | 0 | 0 |
| 29 | Mario Ancic CRO | 3 | 2 | 1 | 0.667 | 0 | 0 |
| 30 | Michael Lammer SUI | 3 | 2 | 1 | 0.667 | 0 | 0 |
| 31 | Ricardas Berankis LTU | 3 | 2 | 1 | 0.667 | 0 | 0 |
| 32 | Carlos Berlocq ARG | 3 | 2 | 1 | 0.667 | 0 | 0 |
| 33 | Brian Dabul ARG | 3 | 2 | 1 | 0.667 | 0 | 0 |
| 34 | Gael Monfils FRA | 17 | 11 | 6 | 0.647 | 0 | 0 |
| 35 | Julien Benneteau FRA | 16 | 10 | 6 | 0.625 | 1 | 2 |
| 36 | Michael Berrer GER | 16 | 10 | 6 | 0.625 | 0 | 0 |
| 37 | Lukasz Kubot POL | 16 | 10 | 6 | 0.625 | 1 | 1 |
| 38 | Illya Marchenko UKR | 8 | 5 | 3 | 0.625 | 0 | 2 |
| 39 | Feliciano Lopez ESP | 13 | 8 | 5 | 0.615 | 0 | 0 |
| 40 | Philipp Kohlschreiber GER | 13 | 8 | 5 | 0.615 | 1 | 0 |