| Rank | Player | Matches | Wins | Losses | PCT | 6-0 | 0-6 |
| 1 | Nikolay Davydenko RUS | 17 | 14 | 3 | 0.824 | 4 | 2 |
| 2 | David Ferrer ESP | 18 | 14 | 4 | 0.778 | 4 | 0 |
| 3 | Tomas Berdych CZE | 16 | 11 | 5 | 0.688 | 3 | 0 |
| 4 | Lleyton Hewitt AUS | 6 | 4 | 2 | 0.667 | 2 | 0 |
| 5 | Juan Ignacio Chela ARG | 12 | 4 | 8 | 0.333 | 2 | 0 |
| 6 | Roger Federer SUI | 13 | 11 | 2 | 0.846 | 2 | 0 |
| 7 | Juan Carlos Ferrero ESP | 19 | 14 | 5 | 0.737 | 2 | 0 |
| 8 | Juan Monaco ARG | 21 | 16 | 5 | 0.762 | 2 | 1 |
| 9 | Harel Levy ISR | 3 | 1 | 2 | 0.333 | 1 | 0 |
| 10 | David Guez FRA | 3 | 0 | 3 | 0.000 | 1 | 0 |
| 11 | Marinko Matosevic AUS | 4 | 1 | 3 | 0.250 | 1 | 0 |
| 12 | Marc Gicquel FRA | 7 | 4 | 3 | 0.571 | 1 | 0 |
| 13 | Rainer Schuettler GER | 7 | 2 | 5 | 0.286 | 1 | 0 |
| 14 | Florian Mayer GER | 9 | 5 | 4 | 0.556 | 1 | 1 |
| 15 | Wayne Odesnik USA | 9 | 4 | 5 | 0.444 | 1 | 0 |
| 16 | Guillermo Garcia-Lopez ESP | 9 | 3 | 6 | 0.333 | 1 | 0 |
| 17 | Radek Stepanek CZE | 10 | 5 | 5 | 0.500 | 1 | 0 |
| 18 | Denis Istomin UZB | 10 | 5 | 5 | 0.500 | 1 | 0 |
| 19 | Olivier Rochus BEL | 10 | 3 | 7 | 0.300 | 1 | 0 |
| 20 | Fabio Fognini ITA | 10 | 3 | 7 | 0.300 | 1 | 2 |
| 21 | Marcel Granollers ESP | 11 | 6 | 5 | 0.545 | 1 | 0 |
| 22 | Tommy Robredo ESP | 11 | 6 | 5 | 0.545 | 1 | 1 |
| 23 | Potito Starace ITA | 11 | 3 | 8 | 0.273 | 1 | 0 |
| 24 | Robin Soderling SWE | 12 | 9 | 3 | 0.750 | 1 | 0 |
| 25 | Jarkko Nieminen FIN | 12 | 6 | 6 | 0.500 | 1 | 0 |
| 26 | Leonardo Mayer ARG | 12 | 6 | 6 | 0.500 | 1 | 2 |
| 27 | Rafael Nadal ESP | 13 | 11 | 2 | 0.846 | 1 | 0 |
| 28 | Philipp Kohlschreiber GER | 13 | 8 | 5 | 0.615 | 1 | 0 |
| 29 | Philipp Petzschner GER | 13 | 7 | 6 | 0.538 | 1 | 0 |
| 30 | Mardy Fish USA | 14 | 7 | 7 | 0.500 | 1 | 1 |
| 31 | Benjamin Becker GER | 14 | 6 | 8 | 0.429 | 1 | 0 |
| 32 | Fernando Verdasco ESP | 15 | 11 | 4 | 0.733 | 1 | 1 |
| 33 | Sam Querrey USA | 15 | 9 | 6 | 0.600 | 1 | 0 |
| 34 | Novak Djokovic SRB | 16 | 13 | 3 | 0.813 | 1 | 1 |
| 35 | Julien Benneteau FRA | 16 | 10 | 6 | 0.625 | 1 | 2 |
| 36 | Lukasz Kubot POL | 16 | 10 | 6 | 0.625 | 1 | 1 |
| 37 | Jurgen Melzer AUT | 18 | 11 | 7 | 0.611 | 1 | 0 |
| 38 | Marcos Baghdatis CYP | 21 | 15 | 6 | 0.714 | 1 | 2 |
| 39 | Andreas Beck GER | 1 | 0 | 1 | 0.000 | 0 | 0 |
| 40 | Fritz Wolmarans RSA | 1 | 0 | 1 | 0.000 | 0 | 0 |