| Rank | Player | Matches | Wins | Losses | PCT | 6-0 | 0-6 |
| 1 | Rafael Nadal ESP | 47 | 42 | 5 | 0.894 | 6 | 1 |
| 2 | Marin Cilic CRO | 39 | 28 | 11 | 0.718 | 5 | 2 |
| 3 | Juan Ignacio Chela ARG | 19 | 8 | 11 | 0.421 | 4 | 0 |
| 4 | Fernando Verdasco ESP | 42 | 30 | 12 | 0.714 | 4 | 0 |
| 5 | Juan Monaco ARG | 33 | 19 | 14 | 0.576 | 3 | 2 |
| 6 | Guillermo Garcia-Lopez ESP | 33 | 18 | 15 | 0.545 | 3 | 1 |
| 7 | Radek Stepanek CZE | 39 | 28 | 11 | 0.718 | 3 | 2 |
| 8 | Roger Federer SUI | 44 | 38 | 6 | 0.864 | 3 | 0 |
| 9 | Tommy Robredo ESP | 47 | 34 | 13 | 0.723 | 3 | 1 |
| 10 | Andy Murray GBR | 51 | 45 | 6 | 0.882 | 3 | 1 |
| 11 | Novak Djokovic SRB | 59 | 47 | 12 | 0.797 | 3 | 0 |
| 12 | Olivier Rochus BEL | 6 | 4 | 2 | 0.667 | 2 | 0 |
| 13 | Ivo Minar CZE | 12 | 4 | 8 | 0.333 | 2 | 0 |
| 14 | Leonardo Mayer ARG | 16 | 8 | 8 | 0.500 | 2 | 0 |
| 15 | Andreas Beck GER | 18 | 10 | 8 | 0.556 | 2 | 0 |
| 16 | Marcel Granollers ESP | 29 | 12 | 17 | 0.414 | 2 | 2 |
| 17 | Marc Gicquel FRA | 29 | 12 | 17 | 0.414 | 2 | 3 |
| 18 | Janko Tipsarevic SRB | 30 | 15 | 15 | 0.500 | 2 | 3 |
| 19 | Fernando Gonzalez CHI | 31 | 24 | 7 | 0.774 | 2 | 0 |
| 20 | Tomas Berdych CZE | 32 | 18 | 14 | 0.563 | 2 | 0 |
| 21 | Jurgen Melzer AUT | 32 | 16 | 16 | 0.500 | 2 | 4 |
| 22 | Albert Montanes ESP | 32 | 16 | 16 | 0.500 | 2 | 2 |
| 23 | Lleyton Hewitt AUS | 34 | 22 | 12 | 0.647 | 2 | 0 |
| 24 | Gilles Simon FRA | 38 | 24 | 14 | 0.632 | 2 | 0 |
| 25 | Jeremy Chardy FRA | 38 | 21 | 17 | 0.553 | 2 | 1 |
| 26 | Andy Roddick USA | 44 | 36 | 8 | 0.818 | 2 | 0 |
| 27 | David Ferrer ESP | 44 | 29 | 15 | 0.659 | 2 | 0 |
| 28 | Caio Zampieri BRA | 1 | 0 | 1 | 0.000 | 1 | 0 |
| 29 | Nicolas Mahut FRA | 4 | 2 | 2 | 0.500 | 1 | 0 |
| 30 | Alexander Peya AUT | 5 | 1 | 4 | 0.200 | 1 | 0 |
| 31 | Vincent Spadea USA | 8 | 2 | 6 | 0.250 | 1 | 0 |
| 32 | Wayne Odesnik USA | 11 | 4 | 7 | 0.364 | 1 | 1 |
| 33 | Pablo Cuevas URU | 12 | 6 | 6 | 0.500 | 1 | 0 |
| 34 | Bobby Reynolds USA | 14 | 3 | 11 | 0.214 | 1 | 1 |
| 35 | Sergiy Stakhovsky UKR | 15 | 6 | 9 | 0.400 | 1 | 0 |
| 36 | Jarkko Nieminen FIN | 15 | 6 | 9 | 0.400 | 1 | 0 |
| 37 | Guillermo Canas ARG | 16 | 4 | 12 | 0.250 | 1 | 0 |
| 38 | Philipp Petzschner GER | 17 | 6 | 11 | 0.353 | 1 | 0 |
| 39 | Steve Darcis BEL | 17 | 4 | 13 | 0.235 | 1 | 0 |
| 40 | Nicolas Devilder FRA | 18 | 4 | 14 | 0.222 | 1 | 0 |