| Rank | Player | Matches | Wins | Losses | PCT | 6-0 | 0-6 |
| 1 | David Ferrer ESP | 56 | 42 | 14 | 0.750 | 7 | 1 |
| 2 | Lleyton Hewitt AUS | 29 | 18 | 11 | 0.621 | 5 | 0 |
| 3 | Nikolay Davydenko RUS | 32 | 22 | 10 | 0.688 | 5 | 2 |
| 4 | Potito Starace ITA | 39 | 19 | 20 | 0.487 | 5 | 1 |
| 5 | Juan Ignacio Chela ARG | 41 | 21 | 20 | 0.512 | 5 | 0 |
| 6 | Philipp Kohlschreiber GER | 44 | 28 | 16 | 0.636 | 5 | 0 |
| 7 | Robin Soderling SWE | 49 | 35 | 14 | 0.714 | 5 | 0 |
| 8 | Mardy Fish USA | 49 | 35 | 14 | 0.714 | 5 | 1 |
| 9 | Rafael Nadal ESP | 60 | 53 | 7 | 0.883 | 5 | 0 |
| 10 | David Nalbandian ARG | 25 | 20 | 5 | 0.800 | 4 | 0 |
| 11 | Richard Gasquet FRA | 43 | 27 | 16 | 0.628 | 4 | 1 |
| 12 | Benjamin Becker GER | 44 | 22 | 22 | 0.500 | 4 | 1 |
| 13 | Juan Carlos Ferrero ESP | 45 | 31 | 14 | 0.689 | 4 | 1 |
| 14 | Roger Federer SUI | 50 | 40 | 10 | 0.800 | 4 | 0 |
| 15 | Tomas Berdych CZE | 54 | 38 | 16 | 0.704 | 4 | 0 |
| 16 | Florent Serra FRA | 37 | 17 | 20 | 0.459 | 3 | 1 |
| 17 | Denis Istomin UZB | 44 | 24 | 20 | 0.545 | 3 | 0 |
| 18 | Albert Montanes ESP | 46 | 29 | 17 | 0.630 | 3 | 1 |
| 19 | Fernando Verdasco ESP | 53 | 38 | 15 | 0.717 | 3 | 3 |
| 20 | Jurgen Melzer AUT | 55 | 35 | 20 | 0.636 | 3 | 0 |
| 21 | Radek Stepanek CZE | 18 | 8 | 10 | 0.444 | 2 | 0 |
| 22 | Taylor Dent USA | 25 | 10 | 15 | 0.400 | 2 | 2 |
| 23 | Florian Mayer GER | 27 | 15 | 12 | 0.556 | 2 | 2 |
| 24 | Marcel Granollers ESP | 31 | 14 | 17 | 0.452 | 2 | 1 |
| 25 | Jarkko Nieminen FIN | 33 | 13 | 20 | 0.394 | 2 | 0 |
| 26 | Janko Tipsarevic SRB | 34 | 17 | 17 | 0.500 | 2 | 2 |
| 27 | Juan Monaco ARG | 35 | 21 | 14 | 0.600 | 2 | 1 |
| 28 | Gael Monfils FRA | 38 | 24 | 14 | 0.632 | 2 | 0 |
| 29 | Thiemo De Bakker NED | 39 | 23 | 16 | 0.590 | 2 | 1 |
| 30 | Philipp Petzschner GER | 39 | 21 | 18 | 0.538 | 2 | 0 |
| 31 | Guillermo Garcia-Lopez ESP | 39 | 21 | 18 | 0.538 | 2 | 0 |
| 32 | Mikhail Youzhny RUS | 42 | 28 | 14 | 0.667 | 2 | 0 |
| 33 | Viktor Troicki SRB | 44 | 23 | 21 | 0.523 | 2 | 1 |
| 34 | Sam Querrey USA | 48 | 32 | 16 | 0.667 | 2 | 0 |
| 35 | Nicolas Almagro ESP | 54 | 37 | 17 | 0.685 | 2 | 1 |
| 36 | Marcos Baghdatis CYP | 57 | 35 | 22 | 0.614 | 2 | 2 |
| 37 | Alessio Di Mauro ITA | 2 | 1 | 1 | 0.500 | 1 | 0 |
| 38 | Alexander Sadecky SUI | 2 | 1 | 1 | 0.500 | 1 | 0 |
| 39 | Harel Levy ISR | 3 | 1 | 2 | 0.333 | 1 | 0 |
| 40 | Martin Klizan SVK | 3 | 1 | 2 | 0.333 | 1 | 1 |