| Rank | Player | Matches | Wins | Losses | PCT | 6-0 | 0-6 |
| 1 | Guillermo Garcia-Lopez ESP | 43 | 21 | 22 | 0.488 | 2 | 5 |
| 2 | Florent Serra FRA | 44 | 20 | 24 | 0.455 | 1 | 4 |
| 3 | Diego Hartfield ARG | 9 | 2 | 7 | 0.222 | 0 | 3 |
| 4 | Jan Hernych CZE | 12 | 4 | 8 | 0.333 | 0 | 3 |
| 5 | Olivier Patience FRA | 13 | 3 | 10 | 0.231 | 0 | 3 |
| 6 | Sergio Roitman ARG | 25 | 7 | 18 | 0.280 | 1 | 3 |
| 7 | Benjamin Becker GER | 31 | 11 | 20 | 0.355 | 0 | 3 |
| 8 | Fabrice Santoro FRA | 35 | 18 | 17 | 0.514 | 1 | 3 |
| 9 | Olivier Rochus BEL | 38 | 13 | 25 | 0.342 | 0 | 3 |
| 10 | Mischa Zverev GER | 40 | 18 | 22 | 0.450 | 0 | 3 |
| 11 | Steve Darcis BEL | 40 | 20 | 20 | 0.500 | 2 | 3 |
| 12 | Rainer Schuettler GER | 44 | 21 | 23 | 0.477 | 2 | 3 |
| 13 | Marat Safin RUS | 46 | 23 | 23 | 0.500 | 1 | 3 |
| 14 | Igor Andreev RUS | 68 | 40 | 28 | 0.588 | 0 | 3 |
| 15 | Fernando Verdasco ESP | 72 | 45 | 27 | 0.625 | 6 | 3 |
| 16 | Robert Smeets AUS | 5 | 0 | 5 | 0.000 | 0 | 2 |
| 17 | Mathieu Montcourt FRA | 5 | 1 | 4 | 0.200 | 0 | 2 |
| 18 | Thierry Ascione FRA | 10 | 1 | 9 | 0.100 | 0 | 2 |
| 19 | Florian Mayer GER | 11 | 2 | 9 | 0.182 | 0 | 2 |
| 20 | Nicolas Devilder FRA | 15 | 4 | 11 | 0.267 | 0 | 2 |
| 21 | Alejandro Falla COL | 17 | 6 | 11 | 0.353 | 0 | 2 |
| 22 | Martin Vassallo Arguello ARG | 18 | 5 | 13 | 0.278 | 0 | 2 |
| 23 | Carlos Berlocq ARG | 19 | 3 | 16 | 0.158 | 0 | 2 |
| 24 | Jonas Bjorkman SWE | 20 | 7 | 13 | 0.350 | 1 | 2 |
| 25 | Pablo Cuevas URU | 21 | 8 | 13 | 0.381 | 0 | 2 |
| 26 | Jiri Vanek CZE | 23 | 7 | 16 | 0.304 | 1 | 2 |
| 27 | Michael Berrer GER | 28 | 8 | 20 | 0.286 | 0 | 2 |
| 28 | Fabio Fognini ITA | 33 | 16 | 17 | 0.485 | 0 | 2 |
| 29 | Denis Gremelmayr GER | 35 | 15 | 20 | 0.429 | 1 | 2 |
| 30 | Dudi Sela ISR | 36 | 14 | 22 | 0.389 | 1 | 2 |
| 31 | Viktor Troicki SRB | 38 | 19 | 19 | 0.500 | 1 | 2 |
| 32 | Oscar Hernandez ESP | 40 | 19 | 21 | 0.475 | 1 | 2 |
| 33 | Nicolas Mahut FRA | 42 | 16 | 26 | 0.381 | 1 | 2 |
| 34 | Julien Benneteau FRA | 42 | 22 | 20 | 0.524 | 4 | 2 |
| 35 | Ernests Gulbis LAT | 43 | 22 | 21 | 0.512 | 2 | 2 |
| 36 | Mario Ancic CRO | 45 | 29 | 16 | 0.644 | 2 | 2 |
| 37 | Janko Tipsarevic SRB | 46 | 25 | 21 | 0.543 | 2 | 2 |
| 38 | Mikhail Youzhny RUS | 46 | 26 | 20 | 0.565 | 3 | 2 |
| 39 | Albert Montanes ESP | 47 | 24 | 23 | 0.511 | 1 | 2 |
| 40 | Jo-Wilfried Tsonga FRA | 47 | 33 | 14 | 0.702 | 2 | 2 |