| Rank | Player | Matches | Wins | Losses | PCT | 6-0 | 0-6 |
| 1 | Olga Govortsova BLR | 42 | 19 | 23 | 0.452 | 2 | 5 |
| 2 | Jill Craybas USA | 37 | 16 | 21 | 0.432 | 2 | 3 |
| 3 | Marion Bartoli FRA | 44 | 23 | 21 | 0.523 | 6 | 3 |
| 4 | Sybille Bammer AUT | 46 | 25 | 21 | 0.543 | 2 | 7 |
| 5 | Dominika Cibulkova SVK | 51 | 30 | 21 | 0.588 | 1 | 2 |
| 6 | Anabel Medina Garrigues ESP | 53 | 32 | 21 | 0.604 | 9 | 2 |
| 7 | Klara Zakopalova CZE | 37 | 17 | 20 | 0.459 | 1 | 2 |
| 8 | Agnes Szavay HUN | 45 | 25 | 20 | 0.556 | 1 | 2 |
| 9 | Camille Pin FRA | 31 | 12 | 19 | 0.387 | 1 | 2 |
| 10 | Virginie Razzano FRA | 33 | 14 | 19 | 0.424 | 1 | 2 |
| 11 | Ai Sugiyama JPN | 43 | 24 | 19 | 0.558 | 2 | 2 |
| 12 | Sara Errani ITA | 45 | 26 | 19 | 0.578 | 3 | 2 |
| 13 | Patty Schnyder SUI | 48 | 29 | 19 | 0.604 | 3 | 2 |
| 14 | Katarina Srebotnik SLO | 53 | 34 | 19 | 0.642 | 11 | 1 |
| 15 | Anastasia Rodionova RUS | 25 | 7 | 18 | 0.280 | 0 | 5 |
| 16 | Elena Vesnina RUS | 30 | 12 | 18 | 0.400 | 1 | 3 |
| 17 | Tathiana Garbin ITA | 31 | 13 | 18 | 0.419 | 1 | 5 |
| 18 | Akgul Amanmuradova UZB | 31 | 13 | 18 | 0.419 | 0 | 2 |
| 19 | Shuai Peng CHN | 34 | 16 | 18 | 0.471 | 3 | 2 |
| 20 | Shahar Peer ISR | 40 | 22 | 18 | 0.550 | 8 | 2 |
| 21 | Anna Chakvetadze RUS | 41 | 23 | 18 | 0.561 | 2 | 0 |
| 22 | Yung-Jan Chan TPE | 29 | 12 | 17 | 0.414 | 1 | 4 |
| 23 | Pauline Parmentier FRA | 31 | 14 | 17 | 0.452 | 1 | 1 |
| 24 | Ekaterina Makarova RUS | 31 | 14 | 17 | 0.452 | 1 | 4 |
| 25 | Kateryna Bondarenko UKR | 31 | 14 | 17 | 0.452 | 1 | 2 |
| 26 | Lucie Safarova CZE | 33 | 16 | 17 | 0.485 | 2 | 1 |
| 27 | Nicole Vaidisova CZE | 34 | 17 | 17 | 0.500 | 3 | 5 |
| 28 | Casey Dellacqua AUS | 35 | 18 | 17 | 0.514 | 0 | 2 |
| 29 | Kaia Kanepi EST | 37 | 20 | 17 | 0.541 | 4 | 4 |
| 30 | Alona Bondarenko UKR | 39 | 22 | 17 | 0.564 | 1 | 4 |
| 31 | Maria Kirilenko RUS | 44 | 27 | 17 | 0.614 | 5 | 1 |
| 32 | Nadia Petrova RUS | 45 | 28 | 17 | 0.622 | 3 | 1 |
| 33 | Victoria Azarenka BLR | 52 | 35 | 17 | 0.673 | 4 | 1 |
| 34 | Flavia Pennetta ITA | 56 | 39 | 17 | 0.696 | 7 | 0 |
| 35 | Martina Muller GER | 22 | 6 | 16 | 0.273 | 1 | 3 |
| 36 | Vania King USA | 23 | 7 | 16 | 0.304 | 0 | 0 |
| 37 | Sofia Arvidsson SWE | 28 | 12 | 16 | 0.429 | 0 | 0 |
| 38 | Aravane Rezai FRA | 30 | 14 | 16 | 0.467 | 1 | 1 |
| 39 | Tsvetana Pironkova BUL | 31 | 15 | 16 | 0.484 | 3 | 1 |
| 40 | Gisela Dulko ARG | 31 | 15 | 16 | 0.484 | 2 | 3 |