| Rank | Player | Matches | Wins | Losses | PCT | 6-0 | 0-6 |
| 1 | Sara Errani ITA | 55 | 31 | 24 | 0.564 | 4 | 1 |
| 2 | Olga Govortsova BLR | 34 | 11 | 23 | 0.324 | 3 | 3 |
| 3 | Anabel Medina Garrigues ESP | 40 | 18 | 22 | 0.450 | 7 | 3 |
| 4 | Sorana Cirstea ROU | 34 | 13 | 21 | 0.382 | 0 | 2 |
| 5 | Melanie Oudin USA | 36 | 15 | 21 | 0.417 | 4 | 2 |
| 6 | Iveta Benesova CZE | 34 | 14 | 20 | 0.412 | 3 | 7 |
| 7 | Stefanie Voegele SUI | 25 | 6 | 19 | 0.240 | 1 | 3 |
| 8 | Jill Craybas USA | 27 | 8 | 19 | 0.296 | 3 | 4 |
| 9 | Magdalena Rybarikova SVK | 30 | 11 | 19 | 0.367 | 2 | 2 |
| 10 | Alize Cornet FRA | 36 | 17 | 19 | 0.472 | 5 | 3 |
| 11 | Yaroslava Shvedova KAZ | 40 | 21 | 19 | 0.525 | 2 | 1 |
| 12 | Alisa Kleybanova RUS | 41 | 22 | 19 | 0.537 | 1 | 2 |
| 13 | Polona Hercog SLO | 41 | 22 | 19 | 0.537 | 5 | 1 |
| 14 | Lucie Safarova CZE | 43 | 24 | 19 | 0.558 | 4 | 1 |
| 15 | Dominika Cibulkova SVK | 44 | 25 | 19 | 0.568 | 4 | 5 |
| 16 | Andrea Petkovic GER | 44 | 25 | 19 | 0.568 | 4 | 3 |
| 17 | Alexandra Dulgheru ROU | 48 | 29 | 19 | 0.604 | 1 | 4 |
| 18 | Aravane Rezai FRA | 52 | 33 | 19 | 0.635 | 2 | 1 |
| 19 | Aleksandra Wozniak CAN | 29 | 11 | 18 | 0.379 | 0 | 2 |
| 20 | Sybille Bammer AUT | 32 | 14 | 18 | 0.438 | 3 | 2 |
| 21 | Elena Vesnina RUS | 33 | 15 | 18 | 0.455 | 2 | 1 |
| 22 | Timea Bacsinszky SUI | 34 | 16 | 18 | 0.471 | 3 | 3 |
| 23 | Anastasia Rodionova AUS | 35 | 17 | 18 | 0.486 | 0 | 2 |
| 24 | Jie Zheng CHN | 41 | 23 | 18 | 0.561 | 1 | 3 |
| 25 | Daniela Hantuchova SVK | 45 | 27 | 18 | 0.600 | 3 | 2 |
| 26 | Flavia Pennetta ITA | 61 | 43 | 18 | 0.705 | 9 | 4 |
| 27 | Alberta Brianti ITA | 24 | 7 | 17 | 0.292 | 2 | 2 |
| 28 | Alla Kudryavtseva RUS | 26 | 9 | 17 | 0.346 | 3 | 3 |
| 29 | Barbora Zahlavova Strycova CZE | 31 | 14 | 17 | 0.452 | 3 | 1 |
| 30 | Roberta Vinci ITA | 34 | 17 | 17 | 0.500 | 3 | 3 |
| 31 | Nadia Petrova RUS | 44 | 27 | 17 | 0.614 | 3 | 3 |
| 32 | Marion Bartoli FRA | 45 | 28 | 17 | 0.622 | 7 | 3 |
| 33 | Maria Kirilenko RUS | 45 | 28 | 17 | 0.622 | 2 | 4 |
| 34 | Na Li CHN | 49 | 32 | 17 | 0.653 | 5 | 0 |
| 35 | Shahar Peer ISR | 55 | 38 | 17 | 0.691 | 7 | 6 |
| 36 | Melinda Czink HUN | 19 | 3 | 16 | 0.158 | 0 | 0 |
| 37 | Lucie Hradecka CZE | 21 | 5 | 16 | 0.238 | 0 | 1 |
| 38 | Tatjana Malek GER | 24 | 8 | 16 | 0.333 | 2 | 4 |
| 39 | Sandra Zahlavova CZE | 24 | 8 | 16 | 0.333 | 1 | 6 |
| 40 | Tathiana Garbin ITA | 25 | 9 | 16 | 0.360 | 1 | 1 |