| Rank | Player | Matches | Wins | Losses | PCT | 6-0 | 0-6 |
| 1 | Julie Coin FRA | 2 | 2 | 0 | 1.000 | 0 | 0 |
| 2 | Lindsay Davenport USA | 26 | 23 | 3 | 0.885 | 3 | 0 |
| 3 | Maria Sharapova RUS | 34 | 30 | 4 | 0.882 | 9 | 0 |
| 4 | Serena Williams USA | 44 | 38 | 6 | 0.864 | 5 | 0 |
| 5 | Justine Henin BEL | 20 | 16 | 4 | 0.800 | 2 | 2 |
| 6 | Elena Dementieva RUS | 53 | 42 | 11 | 0.792 | 7 | 2 |
| 7 | Na Li CHN | 28 | 22 | 6 | 0.786 | 4 | 1 |
| 8 | Dinara Safina RUS | 58 | 45 | 13 | 0.776 | 5 | 1 |
| 9 | Ana Ivanovic SRB | 40 | 31 | 9 | 0.775 | 6 | 1 |
| 10 | Jelena Jankovic SRB | 60 | 46 | 14 | 0.767 | 5 | 0 |
| 11 | Venus Williams USA | 34 | 26 | 8 | 0.765 | 1 | 0 |
| 12 | Agnieszka Radwanska POL | 57 | 43 | 14 | 0.754 | 10 | 1 |
| 13 | Caroline Wozniacki DEN | 56 | 42 | 14 | 0.750 | 11 | 2 |
| 14 | Jie Zheng CHN | 22 | 16 | 6 | 0.727 | 2 | 0 |
| 15 | Vera Zvonareva RUS | 58 | 42 | 16 | 0.724 | 9 | 1 |
| 16 | Anna-Lena Groenefeld GER | 7 | 5 | 2 | 0.714 | 1 | 0 |
| 17 | Svetlana Kuznetsova RUS | 45 | 32 | 13 | 0.711 | 3 | 0 |
| 18 | Flavia Pennetta ITA | 53 | 37 | 16 | 0.698 | 6 | 0 |
| 19 | Victoria Azarenka BLR | 51 | 35 | 16 | 0.686 | 4 | 1 |
| 20 | Alize Cornet FRA | 46 | 31 | 15 | 0.674 | 4 | 1 |
| 21 | Amelie Mauresmo FRA | 39 | 26 | 13 | 0.667 | 4 | 0 |
| 22 | Betina Jozami ARG | 3 | 2 | 1 | 0.667 | 0 | 0 |
| 23 | Margalita Chakhnashvili GEO | 3 | 2 | 1 | 0.667 | 0 | 0 |
| 24 | Petra Martic CRO | 3 | 2 | 1 | 0.667 | 0 | 0 |
| 25 | Tereza Hladikova CZE | 3 | 2 | 1 | 0.667 | 0 | 0 |
| 26 | Patricia Mayr AUT | 3 | 2 | 1 | 0.667 | 0 | 0 |
| 27 | Karolina Pliskova CZE | 3 | 2 | 1 | 0.667 | 0 | 0 |
| 28 | Katalin Marosi HUN | 3 | 2 | 1 | 0.667 | 0 | 1 |
| 29 | Elena Bovina RUS | 3 | 2 | 1 | 0.667 | 0 | 0 |
| 30 | Katarina Srebotnik SLO | 51 | 33 | 18 | 0.647 | 11 | 1 |
| 31 | Nadia Petrova RUS | 44 | 28 | 16 | 0.636 | 3 | 1 |
| 32 | Maria Kirilenko RUS | 44 | 27 | 17 | 0.614 | 5 | 1 |
| 33 | Anabel Medina Garrigues ESP | 53 | 32 | 21 | 0.604 | 9 | 2 |
| 34 | Dominika Cibulkova SVK | 50 | 30 | 20 | 0.600 | 1 | 1 |
| 35 | Patty Schnyder SUI | 45 | 27 | 18 | 0.600 | 3 | 2 |
| 36 | Tamarine Tanasugarn THA | 27 | 16 | 11 | 0.593 | 2 | 1 |
| 37 | Greta Arn HUN | 12 | 7 | 5 | 0.583 | 1 | 1 |
| 38 | Alona Bondarenko UKR | 38 | 22 | 16 | 0.579 | 1 | 4 |
| 39 | Sara Errani ITA | 45 | 26 | 19 | 0.578 | 3 | 2 |
| 40 | Ai Sugiyama JPN | 42 | 24 | 18 | 0.571 | 2 | 2 |