| Rank | Player | Matches | Wins | Losses | PCT | 6-0 | 0-6 |
| 1 | Mariana Duque Marino COL | 5 | 5 | 0 | 1.000 | 2 | 0 |
| 2 | Venus Williams USA | 15 | 14 | 1 | 0.933 | 1 | 0 |
| 3 | Serena Williams USA | 11 | 10 | 1 | 0.909 | 1 | 0 |
| 4 | Elena Dementieva RUS | 21 | 17 | 4 | 0.810 | 2 | 0 |
| 5 | Kim Clijsters BEL | 10 | 8 | 2 | 0.800 | 2 | 2 |
| 6 | Justine Henin BEL | 14 | 11 | 3 | 0.786 | 1 | 0 |
| 7 | Agnieszka Radwanska POL | 13 | 10 | 3 | 0.769 | 5 | 0 |
| 8 | Vera Zvonareva RUS | 17 | 13 | 4 | 0.765 | 5 | 1 |
| 9 | Victoria Azarenka BLR | 16 | 12 | 4 | 0.750 | 4 | 0 |
| 10 | Maria Sharapova RUS | 8 | 6 | 2 | 0.750 | 1 | 0 |
| 11 | Shahar Peer ISR | 23 | 17 | 6 | 0.739 | 3 | 2 |
| 12 | Alona Bondarenko UKR | 11 | 8 | 3 | 0.727 | 0 | 0 |
| 13 | Caroline Wozniacki DEN | 11 | 8 | 3 | 0.727 | 3 | 0 |
| 14 | Anastasia Pavlyuchenkova RUS | 18 | 13 | 5 | 0.722 | 2 | 1 |
| 15 | Yanina Wickmayer BEL | 14 | 10 | 4 | 0.714 | 0 | 0 |
| 16 | Sofia Arvidsson SWE | 7 | 5 | 2 | 0.714 | 0 | 0 |
| 17 | Samantha Stosur AUS | 10 | 7 | 3 | 0.700 | 1 | 0 |
| 18 | Jie Zheng CHN | 16 | 11 | 5 | 0.688 | 1 | 2 |
| 19 | Flavia Pennetta ITA | 18 | 12 | 6 | 0.667 | 2 | 2 |
| 20 | Gisela Dulko ARG | 15 | 10 | 5 | 0.667 | 1 | 2 |
| 21 | Marion Bartoli FRA | 9 | 6 | 3 | 0.667 | 2 | 2 |
| 22 | Angelique Kerber GER | 9 | 6 | 3 | 0.667 | 0 | 0 |
| 23 | Dinara Safina RUS | 6 | 4 | 2 | 0.667 | 0 | 0 |
| 24 | Carla Suarez Navarro ESP | 17 | 11 | 6 | 0.647 | 2 | 1 |
| 25 | Alisa Kleybanova RUS | 17 | 11 | 6 | 0.647 | 0 | 0 |
| 26 | Daniela Hantuchova SVK | 17 | 11 | 6 | 0.647 | 2 | 1 |
| 27 | Maria Kirilenko RUS | 11 | 7 | 4 | 0.636 | 0 | 3 |
| 28 | Jelena Jankovic SRB | 11 | 7 | 4 | 0.636 | 1 | 0 |
| 29 | Petra Kvitova CZE | 8 | 5 | 3 | 0.625 | 1 | 0 |
| 30 | Sara Errani ITA | 18 | 11 | 7 | 0.611 | 1 | 1 |
| 31 | Aravane Rezai FRA | 15 | 9 | 6 | 0.600 | 1 | 0 |
| 32 | Francesca Schiavone ITA | 15 | 9 | 6 | 0.600 | 4 | 2 |
| 33 | Maria Jose Martinez Sanchez ESP | 10 | 6 | 4 | 0.600 | 2 | 0 |
| 34 | Tamarine Tanasugarn THA | 10 | 6 | 4 | 0.600 | 1 | 0 |
| 35 | Anastasija Sevastova LAT | 10 | 6 | 4 | 0.600 | 0 | 0 |
| 36 | Anne Keothavong GBR | 5 | 3 | 2 | 0.600 | 0 | 0 |
| 37 | Chanelle Scheepers RSA | 5 | 3 | 2 | 0.600 | 0 | 0 |
| 38 | Regina Kulikova RUS | 5 | 3 | 2 | 0.600 | 2 | 0 |
| 39 | Agnes Szavay HUN | 17 | 10 | 7 | 0.588 | 0 | 0 |
| 40 | Andrea Petkovic GER | 12 | 7 | 5 | 0.583 | 0 | 0 |